Sunday, January 8, 2012

Dilution of Solutions



When a solution is diluted, more solvent is added to it. 
    Since M = mole/V, and mole is the same for the original solution and the new diluted solution, it follows that M1V1 = M2V2 
    where M1=original concentration of solution 
              V1=original volume of solution 
              M2=new concentration of solution after dilution 
              V2=new volume of solution after dilution



Examples

1.Calculate the new concentration (molarity) if enough water is added to 100mL of 0.25M sodium chloride to make up 1.5L.
M2=(M1V1) ÷ V2
M1 = 0.25M
V1 = 100mL = 100 ÷ 1000 = 0.100L (volume must be in litres)
V2 = 1.5L
[NaCl(aq)]new = M2 = (0.25 x 0.100) ÷ 1.5 = 0.017M 
    (or 0.017 mol/L or 0.017 mol L-1)


2.Calculate the volume to which 500mL of 0.02M coppper sulfate solution must be diluted to make a new concentration of 0.001M.
V2=(M1V1) ÷ M2
M1 = 0.02M
V1 = 500mL = 500 ÷ 1000 = 500 x 10-3L = 0.500L (since there are 1000mL in 1L)
M2 = 0.001M
V(CuSO4)new = V2 = (0.02 x 0.500) ÷ 0.001 = 10.00L







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